|本期目录/Table of Contents|

[1]高继兴,古志峰,杨昌善,等.咪唑基四唑FeII、CoII配合物的[2+3]原位合成、结构及性质研究[J].有色金属科学与工程,2015,(05):73-79.[doi:10.13264/j.cnki.ysjskx.2015.05.014]
 GAO Jixing,GU Zhifeng,YANG Changshan,et al.Synthesis, structures and properties of FeII, CoII-imidazolyl tetrazole compounds through in situ [2+3] synthesis[J].,2015,(05):73-79.[doi:10.13264/j.cnki.ysjskx.2015.05.014]
点击复制

咪唑基四唑FeII、CoII配合物的[2+3]原位合成、结构及性质研究(/HTML)
分享到:

《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2015年05期
页码:
73-79
栏目:
出版日期:
2015-10-20

文章信息/Info

Title:
Synthesis, structures and properties of FeII, CoII-imidazolyl tetrazole compounds through in situ [2+3] synthesis
作者:
高继兴古志峰杨昌善罗燕生谭育慧唐云志
江西理工大学冶金与化学工程学院,江西 赣州 341000
Author(s):
GAO Jixing GU Zhifeng YANG Changshan LUO Yanshen TAN Yuhui TANG Yunzhi
School of Materials and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
关键词:
原位合成 咪唑基 配合物 晶体结构
分类号:
O621.2;TQ031.2
DOI:
10.13264/j.cnki.ysjskx.2015.05.014
文献标志码:
A
摘要:
采用咪唑基配体MID(1-甲基-1H-咪唑-4,5-二甲腈)和NaN3为[2+3]环加成反应原料,分别在FeSO4·7H2O和CoSO4·7H2O作为路易斯酸催化剂条件下进行水热反应,原位合成2个结构新颖的单核咪唑基四唑配合物 [Fe·(MTIC)·(H2O)] (1)和[Co·(MTIC)·(H2O)] (2)及1个配体结构[(MTIC)·(H2O)] (3).结果表明:在化合物1-3中,只有1个氰基发生生成四唑的Sharpless反应,而另一个氰基未发生变化. X-射线单晶衍射分析表明,配合物1-3均结晶于P-1空间群.此外,还对上述配合物进行了元素分析、红外光谱、差热分析和粉末衍射等表征.研究结果对开发新型有机金属超分子结构材料具有一定的指导和借鉴意义.

参考文献/References:

[1] Benson F R. The chemistry of the tetrazoles[J]. Chemical Reviews, 1947, 41(1): 1-61.
[2] Dai L L, Cui S F, Damu L, et al. Recent advances in the synthesis and application of tetrazoles [J]. Chinese Journal of Organic Chemistry, 2013, 33: 224-244.
[3] Zhang H Z, Zhou C H, Geng R X, et al. Recent advances in syntheses of oxazole compounds[J]. Chinese Journal of Organic Chemistry, 2011, 31(12):1963-1976.
[4] Demko Z P, Sharpless K B. Preparation of 5-Substituted 1H-tetrazoles from nitriles in water[J]. Organic Chemistry, 2001, 66: 7945-7950.
[5] 于银梅, 谭育慧, 黄海平, 等. 一个中心对称的(6, 3)拓扑二维蜂窝网的Ni-咪唑基三脚架配合物的合成、结构及其介电性[J]. 有色金属科学与工程, 2014, 4(5): 59-65.
[6] 唐云志, 王艳, 谭育慧, 等. 2,2′-联吡啶-5,5′-二羧酸CuⅡ配合物的构筑、结构及性质研究[J]. 有色金属科学与工程, 2013,4(4): 17-22.
[7] Tang Y Z, Yu Y M, Xiong J B, et al. One pot synthesis, crystal structures and properties of two new MOFs with imidazole-containing tripodal ligand[J]. Science China Chemistry, 2014, 57(11): 1514-1519.
[8] Tang Y Z, Wen H R, Cao Z, et al. A novel three dimensional 3d-4f heterometallic coordination framework with 2,2′-bipyridine-3-carboxylate and oxalate ligands[J]. Inorganic Chemistry Communications, 2010, 13(8): 924-928.
[9] Tan Y H, Xiong J B, Huang J, et al. A familyof tetrazole compounds formed through in situ
[2+3] tetrazole ligand synthesis, structures and fluorescent properties[J]. Chinese Journal of Inorganic Chemistry, 2014, 30 (7): 1621-1628.
[10] Tang Y Z, Zhou M, Huang J, et al. In situ synthesis and ferroelectric, SHG response, and luminescent properties of a novel 3D acentric zinc coordination polymer[J]. Inorganic Chemistry, 2013, 52(4): 1679-1681.
[11] Tan Y H, Wu J J, Yang L F, et al. Anion and pH induced spontaneous resolution of Δ- and Λ-[M(H2Biim)3]SO4 (M=Ru2+, Co2+, Ni2+,Mn2+,Fe2+,and Zn2+) enantiomers[J]. CrystEngComm, 2012, 14: 8117-8123.
[12] Zhang W, Xiong R G. Ferroelectric metal-organic frameworks[J]. Chemical Reviews, 2012, 112(2): 1163-1195.
[13] Zhao H, Qu Z R, Ye H Y, et al. In situ hydrothermal synthesis of tetrazole coordination polymers with interesting physical properties[J]. Chemical Society Reviews, 2008, 37(1): 84-100.
[14] Yang L N, Li J, Zhang F X. Tri (2,2′-biimidazole) nickel (Ⅱ) phthalate[J]. Acta Crystallographica Section E Structure Reports Online, 2005, 61(10): 2169-2171.
[15] Li X P, Pan M, Zheng S R, et al. Dimension-increase via hydrogen bonding and weak coordination interactions from simple complexes of 2-(pyridyl) benzimidazole ligands[J]. Crystal Growth and Design, 2007, 7(12): 2481-2490.
[16] Li X P, Zhang J Y, Pan M, et al. Zero to three dimensional increase of silver (Ⅰ) coordination assemblies controlled by deprotonation of 1,3,5-tri(2-denzimidazolyl) benzene and aggregation of multinuclear building units[J]. Inorganic Chemistry, 2007, 46(11): 4617-4625.
[17] Himo F, Demko Z P, Sharpless K. B, et al. Mechanisms of tetrazole formation by addition of azide to nitriles[J]. Journal of the American Chemical Society, 2002, 124:12210-12216.
[18] Himo F, Demko Z P, Sharpless K. B, et al. Why is tetrazole formation by addition of azide to organic nitriles catalyzed by zinc(II) salts[J]. J. Am. Chem. Soc., 2003, 125:9983-9987.
[19] Sheldrick G M. SHELXS-97, Programs zur losung von kristall-strukturen[M]. Gottingen: University of Grttingen, 1997: 509-771.
[20] Sheldrick G M. SHELXS-97, Programs for X-ray crystal structure refinement[M]. Gottingen:University of Grttingen, 1997: 208-311.
[21] Li Z , Li M, Zhou X P, et al. Metal directed supramolecular architectures: from mononuclear to 3D frameworks based on in situ tetrazole ligand synthesis[J]. Crystal Growth and Design, 2007, 7(7): 1992-1998.
[22] Qu Z R, Zhao H, Wang X S, et al. Homochiral Zn and Cd coordination polymers containing amino acid-tetrazole ligands[J]. Inorganic Chemistry, 2003, 42(18): 7710-7712.
[23] 苏成勇, 潘梅. 配位超分子结构化学基础与进展[M].北京:科学出版社, 2010.
[24] 艾浩, 漆婷婷, 包俊, 等. 稀土Dy单分子磁体的研究进展[J]. 有色金属科学与工程, 2013,4(6): 82-91.
[25] 谭秀珍, 陈景林, 曹兴付, 等. 一价铜卤化物的设计合成与晶态结构研究[J]. 有色金属科学与工程, 2013,4(1): 31-36.

相似文献/References:

[1]朱二涛,张久兴,杨新宇,等.Co对原位合成WC-6Co复合粉末制备高性能硬质合金的影响[J].有色金属科学与工程,2019,(06):31.[doi:10.13264/j.cnki.ysjskx.2019.06.006]
 ZHU Ertao,ZHANG Jiuxing,YANG Xinyu,et al.Research of Co in high performance cemented carbide produced from In-situ synthesis WC-6Co composite powder[J].,2019,(05):31.[doi:10.13264/j.cnki.ysjskx.2019.06.006]

备注/Memo

备注/Memo:
收稿日期:2015-04-21基金项目:国家自然科学基金资助项目(21471070, 21261009);江西省青年科学家人才基金项目作者简介:高继兴(1987- ),男,硕士研究生,研究方向为铁-介电材料组装,E-mail: jixing8928@126.com.通信作者:唐云志(1975- ),男,博士,教授,研究方向为光电磁功能配合物,E-mail: tangyunzhi75@163.com.
更新日期/Last Update: 2015-10-30