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[1]肖青辉,宋碧清,杨军,等.高Eu3+浓度掺杂硼铋钙红光玻璃的制备与发光性能研究[J].有色金属科学与工程,2018,(05预):17-22.
 XIA Libin.Preparation and luminescence properties of calcium bismuth borate red-light glass doped with high concentration Eu 3+ XIAO Qinghui1,SONG Biqing2,YANG Jun1,LI Zicheng1,YOU Weixiong1,[J].,2018,(05预):17-22.
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高Eu3+浓度掺杂硼铋钙红光玻璃的制备与发光性能研究(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2018年05期预
页码:
17-22
栏目:
出版日期:
2018-09-20

文章信息/Info

Title:
Preparation and luminescence properties of calcium bismuth borate red-light glass doped with high concentration Eu 3+ XIAO Qinghui1,SONG Biqing2,YANG Jun1,LI Zicheng1,YOU Weixiong1,
作者:
肖青辉1 宋碧清2杨军1 李子成1 游维雄1 夏李斌1
(1江西理工大学 材料科学与工程学院,江西 赣州 341000;2 江西优信普科技有限公司,江西 龙南 341700)
Author(s):
XIA Libin1
(1. School of Materials Science and EngineeringJiangxi University of Science and TechnologyGanzhou 341000China 2. Jiangxi Youxinpu Technology Company Longnan 341700China)
关键词:
Eu3+ 红光 硼铋酸盐玻璃 白光LED
分类号:
O482.31;TQ127.2
DOI:
-
文献标志码:
A
摘要:
采用传统熔融冷却法制备了Eu3+掺杂的硼铋钙红光玻璃,研究了不同Eu3+掺杂浓度下,玻璃的密度、摩尔体积、折射率等一般物理性质的变化规律;分析了玻璃的激发、发射光谱及玻璃的结构和热稳定性,得到了一种高Eu3+掺杂浓度的红光玻璃。研究表明:随着Eu3+浓度的不断升高,玻璃的密度、折射率、玻璃转化温度和热稳定性逐渐升高,摩尔体积先减小后增大;8 mol%为Eu2O3的最佳掺杂浓度, 9 mol%为玻璃成玻区中最大Eu2O3掺杂浓度。玻璃总体对称性均较低,为非晶态结构;玻璃结构致密程度先增大后减小,其结构单元主要包括[BO3]三角体、[BO4]四面体、[BiO3]三角体和[BiO6] 八面体。制备的荧光玻璃因具有高的Eu3+掺杂浓度、与蓝光芯片的有效匹配度、优良的热稳定性、较低的熔点以及合适的折射率等特点,将有望成为白光LED用玻璃陶瓷的良好基质。

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相似文献/References:

[1]肖青辉,宋碧清,杨军,等.高Eu3+浓度掺杂硼铋钙红光玻璃的制备与发光性能研究[J].有色金属科学与工程,2018,(05):90.[doi:10.13264/j.cnki.ysjskx.2018.05.015]
 XIAO Qinghui,SONG Biqing,YANG Jun,et al.Preparation and luminescence properties of calcium bismuthborate red-lightglass doped with high concentration Eu3+[J].,2018,(05预):90.[doi:10.13264/j.cnki.ysjskx.2018.05.015]

备注/Memo

备注/Memo:
-
更新日期/Last Update: 2018-09-14