|本期目录/Table of Contents|

[1]钟盛文,王玉娥,张 骞,等.LiNi0.5Mn0.5O2的合成及其AA电池电化学性能[J].有色金属科学与工程,2010,(02):11-15.
 ZHANG Sheng-wen,WANG Yue,ZHANG Qian,et al.Synthesis and Electrochemical Properties of LiNi0.5Mn0.5O2 as Cathode Material for AA Lithium Ion Batteries[J].,2010,(02):11-15.
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LiNi0.5Mn0.5O2的合成及其AA电池电化学性能(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2010年02期
页码:
11-15
栏目:
冶金·材料
出版日期:
2010-04-30

文章信息/Info

Title:
Synthesis and Electrochemical Properties of LiNi0.5Mn0.5O2 as Cathode Material for AA Lithium Ion Batteries
作者:
钟盛文 王玉娥  张 骞  乔晓宁
江西理工大学材料与化学工程学院,江西 赣州 341000
Author(s):
ZHANG Sheng-wen WANG Yu′e ZHANG Qian QIAO Xiao-ni
Faculty of Materiai and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
关键词:
锂离子电池正极材料共沉淀电化学性能LiNi0.5Mn0.5O2
分类号:
TF122.3;TM911.14
DOI:
-
文献标志码:
A
摘要:
采用共沉淀法合成LiNi0.5Mn0.5O2正极材料.采用X射线衍射(XRD)和扫描电镜(SEM)表征合成材料的结构和形貌.研究不同Li/(Mn+Ni)摩尔比、不同焙烧制度、不同化成制度对LiNi0.5Mn0.5O2的电化学性能的影响.结果表明,当Li/(Mn+Ni)摩尔比1.08、一次焙烧温度为500℃,二次焙烧温度为850℃下焙烧得到的材料电化学性能最佳.

参考文献/References:

[1] Meng X L, Dou S M, Wang W L. High Power and High Capacity Cathode Material LiNi0.5Mn0.5O2 for Advanced Lithium-ion Batteries [J].Journal of Power Sources, 2008,184:489-493.
[2] Kang S H ,Kim J,Stoll M E, et al.Layered Li(Ni0.5-xMn0.5-xM′(2x))O2 (M'=Co,Al,Ti;x=0,0.025)Cathode Materials for Li-ion Rechargeable  Batteries[J].Journal of Power Sources,2002,(1):41-48.
[3] 彭小琦,王志兴,李新海,等.正极材料LiNi0.5Mn0.5O2的合成及其 性能研究[J].电源技术,2006,30(4):301-304.
[4] 肖 劲,曾雷英,陈召勇,等.离子电池正极材料LiNi0.5Mn0.5O2的合  成 [J].无机化学学报,2006,22(4):685-690.
[5] 曹四海,王志兴,李新海,等.固相法制备层状LiNi0.5Mn0.5O2的研究 [J].电池工业,2006,11(3):178-181.
[6] 王志兴,曹四海,李新海,等.初始Li/(Mn+Ni)摩尔比对LiNi0.5Mn0.5O2 材料电化学性能的影响[J].中国有色金属学报,2006,16(8):1434- 1438.
[7] Park S H ,Kang S H ,Johnson C S,et al.Lithium-manganese-nickel- oxide Electrodes with Integrated Layered-spinel Structures for Lithi- um Batteries[J].Electrochemistry Communications,2007,(9):262-268.
[8] Makimura Y,Ohzuku T.Lithium Insertion Material of LiNi0.5Mn0.5O2 for Advanced Lithium-ion batteries[J].Journal of PowerSources, 2003, 119(Sp.Iss.SI):156-160.
[9] Li D.C,Sasaki Y,Kobayakawa K,et al.Mpact of Cobalt Substitution for Manganese on the Structural and Electrochemical Properties of LiNi0.5Mn0.5O2[J].Electrochimica Acta,2006,51(18):3809-3813.
[10] Numata K,aki C,amanaka S.Synthesis and Characterization of Layer Structured SDolid Solutions in the System of LiCoO2-Li2MnO3[J]. Solid State Ionics,1999,117:257.
[11] Lu Z J,Dahn R.A Comparison of the Electrode/Electrolyte Reaction at Elevated Temperatures for Various Lo-ion Battery Cathodes[J].J Electrochem Soc,2002,108:8-14.
[12] 钟清华,袁中直.层状的LiNi0.5Mn0.5O2合成及其电化学性能[J].电 源技术, 2009,33(7): 543-546.
[13] Paulsen J M,Thomas C L,Dahn J R.O2 Structure Li2/3[Ni1/3Mn2/3]O2:a New Layered Cathode Material for Rechargeable Lithium Batteries I [J].Electrochemical Properties J Electrochem Soc,2000,147(3):861.

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备注/Memo

备注/Memo:
收稿日期:2010-11-06 基金项目:国家自然科学基金资助项目(50762004) 作者简介:钟盛文(1963-     ),男,博士,教授.
更新日期/Last Update: 2011-01-20