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[1]钟盛文,王玉娥,张 骞,等.LiNi0.5Mn0.5O2的合成及其AA电池电化学性能*[J].有色金属科学与工程,2016,(05预):2030-2034.
 WANG Yu-e,ZHONG Sheng-Wen,ZHANG Qian,et al.Synthesis and Electrochemical Properties of LiNi0.5Mn0.5O2 as Cathode Material for AA Lithium ion batteries[J].,2016,(05预):2030-2034.
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LiNi0.5Mn0.5O2的合成及其AA电池电化学性能*(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2016年05期预
页码:
2030-2034
栏目:
出版日期:
2016-10-31

文章信息/Info

Title:
Synthesis and Electrochemical Properties of LiNi0.5Mn0.5O2 as Cathode Material for AA Lithium ion batteries
作者:
钟盛文王玉娥 张 骞 乔晓宁
(江西理工大学材料与化学工程学院 江西赣州 341000)
Author(s):
WANG Yu-eZHONG Sheng-WenZHANG QianQIAO Xiao-ni
(School of Materiais and Chemical Engineering,Jiangxi University of Science&Technology,Ganzhou Jiangxi,341000,China)
关键词:
锂离子电池正极材料共沉淀电化学性能LiNi0.5Mn0.5O2
分类号:
-
DOI:
-
文献标志码:
-
摘要:
采用共沉淀法合成LiNi0.5Mn0.5O2正极材料。采用X射线衍射(XRD)和扫描电镜(SEM)表征了合成材料的结构和形貌。研究了不同Li/(Mn+Ni)摩尔比、不同焙烧制度、不同化成制度对LiNi0.5Mn0.5O2的电化学性能的影响。结果表明,当Li/(Mn+Ni)摩尔比1.08、一次焙烧温度为500℃,二次焙烧温度为850℃下焙烧得到的材料电化学性能最佳。

参考文献/References:

[1] Meng X L, Dou S M, Wang W L. High power and high capacity cathode material LiNi0.5Mn0.5O2 for advanced lithium-ion batteries[J].Journal of Power Sources 184(2008)489-493.
[2]Kang S.H.,Kim J,Stoll M.E.et al.Layered Li(Ni0.5-xMn0.5-xM’(2x))O2(M’=Co,Al,Ti;x=0,0.025)cathode materials for Li-ion rechargeable batteries[J].Journal of Power Sources,2002,(1):41-48.
[3]彭小琦,王志兴,李新海等。正极材料LiNi0.5Mn0.5O2的合成及其性能研究[J].电源技术,2006,30(4):301-304
[4]肖劲,曾雷英,陈召勇等。离子电池正极材料LiNi0.5Mn0.5O2的合成[J].无机化学学报,2006,22(4):685-690
[5]曹四海,王志兴,李新海等。固相法制备层状LiNi0.5Mn0.5O2的的研究[J].电池工业,2006,11(3):178-181
[6]王志兴,曹四海,李新海等。初始Li/(Mn+Ni)摩尔比对LiNi0.5Mn0.5O2材料电化学性能的影响[J]。中国有色金属学报,2006,16(8):1434-1438.
[7]Park S.H.,Kang,S.H.,Johnson,C.S.et al.Lithium-manganese-nickel-oxide electrodes with integrated layered-spinel structures
for lithium batteries[J].Electrochemistry Communications,2007,(9):262-268.
[8]Makimura Y,Ohzuku T.Lithium insertion material of LiNi0.5Mn0.5O2 for advanced lithium-ion batteries[J].Journal of PowerSources,2003,119(Sp.Iss.SI):156-160.
[9]Li D.C,Sasaki Y,Kobayakawa K,et al.mpact of cobalt substitution for manganese on the structural and electrochemical properties of LiNi0.5Mn0.5O2[J].Electrochimica Acta,2006,51(18):3809-3813.
[10] Numata K,aki C,amanaka S.Synthesis and characterization of layer structured solid solutions in the system of LiCoO2-Li2MnO3[J].Solid State Ionics,1999,117:257.
[11] Lu Z J,Dahn R.A comparison of the electrode/electrolyte reaction at elevated temperatures for various Lo-ion battery cathodes[J].J Electrochem Soc,2002,108:8-14.
[12]钟清华,袁中直。层状的LiNi0.5Mn0.5O2合成及其电化学性能[J].电源技术, 2009,33(7): 543-546
[13] Paulsen J M,Thomas C L,Dahn J R.O2 structure Li2/3[Ni1/3Mn2/3]O2:a new layered cathode material for rechargeable lithium batteries I[J].Electrochemical Properties J Electrochem Soc,2000,147(3):861.

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备注/Memo

备注/Memo:
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更新日期/Last Update: 2016-04-08