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[1]何丽华a,陈景林b,曹兴付b,等.2-(2-苯并咪唑基)-6-甲基吡啶铜(I)溴化物的合成与发光[J].有色金属科学与工程,2012,(03):6-9.
 HE Li-huaa,CHEN Jing-linb,CAO Xing-fub,et al.Synthesis and luminescence of cuprous bromide compound of 2-(2-benzimidazolyl)-6-methylpyridine[J].,2012,(03):6-9.
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2012年03期
页码:
6-9
栏目:
出版日期:
2012-06-30

文章信息/Info

Title:
Synthesis and luminescence of cuprous bromide compound of 2-(2-benzimidazolyl)-6-methylpyridine
作者:
何丽华a 陈景林b 曹兴付b 陈琇琇b 谭秀珍b 温和瑞b
江西理工大学, a.理学院; b.冶金与化学工程学院, 江西 赣州 341000
Author(s):
HE Li-huaa CHEN Jing-linb CAO Xing-fub CHEN Xiu-xiub TAN Xiu-zhenb WEN He-ruib
a. Faculty of Science; b. School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
关键词:
一价铜配合物氮杂环螯合配体晶体结构光致发光性质
分类号:
TF811
DOI:
-
文献标志码:
A
摘要:
一价铜配合物因具有丰富的光物理性质和良好的潜在应用而被广泛研究.文中选用2-(2-苯并咪唑基)-6-甲基吡啶(Hbmp)作为二齿螯合配体,与溴化亚铜和三苯基膦进行分子组装反应,合成得到一单核的一价铜溴化物[Cu(Hbmp)(PPh3)Br] (1),并对其晶态结构特征和固态光致发光性能进行了研究. 研究表明:配合物1的中心铜原子采取四配位方式,分别与一个溴、一个磷和两个氮原子相连,这四个配位的原子共同组成一个变型的四面体构型,这些相邻的配合物分子又通过Hbmp配体间存在的弱π-π作用发生有序堆叠排列并形成一维的链状结构. 配合物1在室温下表现出强的固态光致磷光发射,其磷光发射主要来源于金属到配体和卤素到配体两种电荷转移跃迁.

参考文献/References:

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相似文献/References:

[1]陈景林,宋 鹏,温和瑞,等.双核铜(I)合物的合成及其固态发光性质的研究[J].有色金属科学与工程,2010,(01):27.
 CHEN Jing-lin,SONG Peng,WEN He-rui,et al.Syntheses and Solid-state Luminescence Properties of Binuclear Copper (I) Complexes[J].,2010,(03):27.

备注/Memo

备注/Memo:
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更新日期/Last Update: 2012-06-30