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[1].文章编号:一价铜卤化物的设计合成与晶态结构研究[J].有色金属科学与工程,2016,(05预):1425-1429.
 TAN Xiu-zhen,CHEN Jing-lin,CAO Xing-fu,et al.Designed synthesis and crystalline structure of copper(I) halide complexes[J].,2016,(05预):1425-1429.
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文章编号:一价铜卤化物的设计合成与晶态结构研究(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2016年05期预
页码:
1425-1429
栏目:
出版日期:
2016-10-31

文章信息/Info

Title:
Designed synthesis and crystalline structure of copper(I) halide complexes
作者:
-
Author(s):
TAN Xiu-zhen CHEN Jing-lin CAO Xing-fu CHEN Xiu-xiu ZHANG Feng WEN He-rui LIAO Jin-sheng
(Faculty of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China)
关键词:
一价铜卤化物双膦配体晶体结构三核配合物双核配合物
分类号:
TF811
DOI:
-
文献标志码:
A
摘要:
文中以1,2-双(二苯基膦)乙烷(dppe)、1,4-双(二苯基膦)丁烷(dppb)和卤化亚铜作为初始原料,合成得到一个三核铜(I)溴化物[{Cu2(μ-dppe)(μ-Br)2}(μ-dppe)2CuBr] (1) 和一个双核铜(I)碘化物[{Cu(dppb)I}2(μ-dppb)] (2). X-射线单晶衍射表明:配合物1为三核铜配合物,Cu1和Cu2两原子采用常见的四配位方式,分别与两个Br原子和两个P原子连接构成一个变型四面体,而Cu3原子采取三配位模式,与一个Br和两个P原子相连接形成一个平面三角形, Cu1、Cu2和Cu3这三个铜原子又共同构成了一个近似等腰的平面三角形;配合物2为双核铜配合物,三个dppb配体表现出两种配位方式:两个以二齿螯合方式分别与一个Cu原子连接,一个以桥联方式与两个相同的{Cu(dppb)I}砌块相连接

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相似文献/References:

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备注/Memo

备注/Memo:
收稿日期:基金项目:国家自然科学基金项目(21001057、21163009);国家教育部科学技术研究重点项目(211088);国家留学人员科技活动项目择优资助(赣人社字[2011]474号);江西省青年科学家(井冈之星)培养计划资助项目(20122BCB23016);结构化学国家重点实验室科学基金项目(20110015)作者简介:谭秀珍(1990– ),女,汉,硕士研究生,主要从事功能配合物化学研究,E–mail:tanxiuzhen123456@126.com通信作者:陈景林(1976– ),男,汉,博士,教授,主要从事光电功能材料与器件研究,E–mail:gzchenjinglin@126.com
更新日期/Last Update: 2016-04-01