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[1]谭秀珍,陈景林,曹兴付,等.一价铜卤化物的设计合成与晶态结构研究[J].有色金属科学与工程,2013,(01):31-36.
 TAN Xiu-zhen,CHEN Jing-lin,CAO Xing-fu,et al.Design synthesis and crystalline structure of copper(I) halide complexes[J].,2013,(01):31-36.
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一价铜卤化物的设计合成与晶态结构研究(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2013年01期
页码:
31-36
栏目:
出版日期:
2013-02-28

文章信息/Info

Title:
Design synthesis and crystalline structure of copper(I) halide complexes
作者:
谭秀珍 陈景林 曹兴付 陈琇琇 张 凤 温和瑞 廖金生
江西理工大学冶金与化学工程学院, 江西 赣州 341000
Author(s):
TAN Xiu-zhen CHEN Jing-lin CAO Xing-fu CHEN Xiu-xiu ZHANG Feng WEN He-rui LIAO Jin-sheng
School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
关键词:
一价铜卤化物双膦配体晶体结构三核配合物双核配合物
分类号:
TF811; O641
DOI:
-
文献标志码:
A
摘要:
以1,2-双(二苯基膦)乙烷(dppe)、1,4-双(二苯基膦)丁烷(dppb)和卤化亚铜作为初始原料,合成得到1个三核铜(I)溴化物[{Cu2(μ-dppe)(μ-Br)2}(μ-dppe)2CuBr] (1) 和1个双核铜(I)碘化物 [{Cu(dppb)I}2(μ-dppb)] (2). X-射线单晶衍射表明:配合物1为三核铜配合物,Cu1和Cu2两原子采用常见的四配位方式,分别与2个Br原子和2个P原子连接构成1个变型四面体,而Cu3原子采取三配位模式,与1个Br和2个P原子相连接形成1个平面三角形, Cu1、Cu2和Cu3这3个铜原子又共同构成了1个近似等腰的平面三角形;配合物2为双核铜配合物,3个dppb配体表现出2种配位方式:2个以二齿螯合方式分别与1个Cu原子连接,1个以桥联方式与2个相同的{Cu(dppb)I}砌块相连接.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2012-09-11 基金项目:国家自然科学基金资助项目(21001057、21163009);国家教育部科学技术研究重点项目(211088);国家留学人员科技活动项目择优资助(赣人社字[2011]474号);江西省青年科学家(井冈之星)培养计划资助项目(20122BCB23016);结构化学国家重点实验室科学基金项目(20110015) 作者简介:谭秀珍(1990- ),女,硕士研究生,主要从事功能配合物化学研究,E-mail:tanxiuzhen123456@126.com.
更新日期/Last Update: 2013-03-10