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[1]舒庆*,侯小鹏,刘峰生,等.稀土镧改性磷钨杂多酸盐催化油酸与甲醇酯化反应合成生物柴油活性研究[J].有色金属科学与工程,2016,(05预):95-099.
 SHU Qing,HOU Xiao-peng,LIU Feng-sheng,et al.Studies on the Catalytic Activity of La-Modified Phosphotungstic Heteropoly Acid Salt in the Synthesis of Biodiesel from the Esterification of Methanol and Oleci Acid[J].,2016,(05预):95-099.
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稀土镧改性磷钨杂多酸盐催化油酸与甲醇酯化反应合成生物柴油活性研究(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2016年05期预
页码:
95-099
栏目:
出版日期:
2016-10-31

文章信息/Info

Title:
Studies on the Catalytic Activity of La-Modified Phosphotungstic Heteropoly Acid Salt in the Synthesis of Biodiesel from the Esterification of Methanol and Oleci Acid
作者:
舒庆*侯小鹏刘峰生唐国强许宝泉张彩霞
(江西理工大学冶金与化学工程学院,江西 赣州 34100)
Author(s):
SHU Qing HOU Xiao-peng LIU Feng-sheng TANG Guo-qiang XU Bao-quan Zhang Cai-xia
(School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China)
关键词:
稀土杂多酸盐酯化反应生物柴油
分类号:
TQ 645. 8
DOI:
-
文献标志码:
A
摘要:
以H3PW12O40和La(NO3)3为原料,通过离子交换法制备了一种稀土镧改性磷钨杂多酸盐催化剂.通过扫描电镜、红外光谱和X射线粉末衍射等表征方法,对合成的催化剂的物理及化学性能进行了分析,进而通过以油酸和甲醇为反应物的酯化反应,对其催化活性进行了研究.结果表明:稀土镧已经导入了磷钨杂多酸的骨架结构,并与杂原子P形成了配位键,有效提高了磷钨杂多酸的比表面积和孔径;合成的催化剂具有完整的Keggin型结构;当反应温度为62°C,油酸与甲醇摩尔比为1:6,反应时间为4.5 h,催化剂用量为反应物质量的2.5 %,油酸的转化率可达88.0 %

参考文献/References:

[1] Xu YJ, Li GX, Sun ZY. Development of?biodiesel?industry in China: Upon the terms of production and consumption[J]. Renewable and Sustainable Energy Reviews, 2016, 54: 318-330.
[2] Sultana N, Pathak AK, Guria C. Response surface method and genetic algorithm assisted optimal synthesis of?biodiesel?from high free fatty acid sal oil (Shorea robusta) using ion-exchange resin at high temperature[J]. Journal of Environmental Chemical Engineering,?2015,?3: 2378-2392.
[3] Olkiewicz M, Plechkova NV, Earle M J, et al. Biodiesel?production from sewage sludge lipids catalysed by Br?nsted acidic ionic liquids[J]. Applied Catalysis B: Environmental, 2016, 181: 738-746.
[4] André GB, Virginia P. Organic municipal solid waste (MSW) as feedstock for?biodiesel?production: A financial feasibility analysis[J]. Renewable Energy, 2016, 86: 1422-1432.
[5] Peng BX, Shu Q, Wang JF, et al. Biodiesel production from waste oil feedstocks by solid acid catalysis[J]. Process Safety and Environmental Protection, 2008, 86:441-447.
[6] Theam KL, Islam A, Choo YM, et al. Biodiesel?from low cost palm stearin using metal doped methoxide solid catalyst[J]. Industrial Crops and Products, 2015,?76: 281-289.
[7] Ruth G, Piyali B, Asim B. Sulfonated porous organic polymer as a highly efficient catalyst for the synthesis of?biodiesel?at room temperature[J]. Journal of Molecular Catalysis A: Chemical,?2016,?411: 110-116.
[8] Bárbara SC, Cátia SN, Paulo RS, et al. Supercritical ethanolysis for?biodiesel?production from edible oil waste using ionic liquid [HMim][HSO4] as catalyst[J]. Applied Catalysis B: Environmental, 2016, 181: 289-297.
[9] Gong SW, Lu J, Wang HH, et al. Biodiesel?production via esterification of oleic?acid?catalyzed by picolinic?acid?modified 12-tungstophosphoricacid[J]. Applied Energy,?2014, 134: 283-289.
[10] Zou CJ, Zhao PW, Shi LH, et al. Biodiesel?fuel production from waste cooking oil by the inclusion complex of?heteropoly?acid?with bridged bis-cyclodextrin[J]. Bioresource Technology, 2013,?146: 785-788.
[11] Amin TK, Nor ASA, Alireza Z, et al. Transesterification of waste cooking oil by?heteropoly?acid?(HPA) catalyst: Optimization and kinetic model[J]. Applied Energy,?2013,?102: 283-292.
[12] 舒庆, 刘宝, 宋胜海, 等. 钨钼混配型杂多酸盐催化剂上酯化反应条件的优化研究[J].有色金属科学与工程, 2014, 5: 521-27.
[13] Naonobu K, Tsubasa H, Mitsuo O, et al. Biodiesel?production using?heteropoly?acid-derived solid?acid?catalyst H4PNbW11O40/WO3–Nb2O5[J]. Applied Catalysis A: General,?2009, 363: 164-168.
[14] Nilesh N, Varsha B, Anjali P. Efficient synthesis of?biodiesel?from waste cooking oil using solid?acid?catalyst comprising 12-tungstosilicic?acid?and SBA-15[J]. Fuel,?2014,?135: 253-261.
[15] Varsha B, Anjali P. 12-Tungstophosphoric?acid?anchored to SBA-15: An efficient, environmentally benign reusable catalysts for?biodieselproduction by esterification of free fatty?acids[J]. Applied Catalysis A: General,?2011, 403: 161-172.

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备注/Memo

备注/Memo:
*基金项目:国家自然科学基金资助项目(21206062,21466013);江西省2014年度自然科学青年基金重大项目(20143ACB21018)作者简介:舒 庆(1979- ),男,博士,副教授,主要从事能源化工、催化反应工程和反应器设计方面的研究工作,
更新日期/Last Update: 2016-03-29