|本期目录/Table of Contents|

[1]黄蒙蒙,李宏煦,刘召波.不同二次资源中镓提取方法的研究进展[J].有色金属科学与工程,2017,(01预):30-35.
　Mengmeng Huang,Hongxu Li,Zhaobo Liu.Research progress on gallium extraction from different secondary resources[J].,2017,(01预):30-35.
点击复制

不同二次资源中镓提取方法的研究进展(/HTML)
分享到：

《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2017年01期预
页码:
30-35
栏目:
出版日期:
2017-01-30

文章信息/Info

Title:
Research progress on gallium extraction from different secondary resources
作者:
黄蒙蒙1; 2; 李宏煦1; 2; 刘召波1; 2
北京科技大学冶金与生态工程学院,北京,100083; 2. 稀贵金属绿色回收与提取北京市重点实验室,北京,100083)
Author(s):
Mengmeng Huang12;  Hongxu Li12;  Zhaobo Liu12
(1. School of metallurgical and Ecological Engineering, University of Science and Technology Beijing, 100083 2. Beijing Key Laboratory of green recovery and extraction of precious metals, Beijing 100083)
关键词:
镓; 赤泥; 锌浸出渣; 粉煤灰; 电子垃圾
分类号:
-
DOI:
-
文献标志码:
-
摘要:
镓作为稀散金属之一，在光纤通信、航空航天、电子技术等领域具有广阔的应用前景，随着近几年电子产业的发展，镓出现了供不应求的局面。镓在自然界中没有独立的成矿，由于它的某些物理化学性质同铝、铁、锌等相似，常伴生在铝土矿、铅锌矿、煤及钛铁矿中，因此这些矿物中的镓在湿法、火法冶金过程中得以富集在比如氧化铝生产过程中的副产物，湿法炼锌过程中的浸出渣，煤燃烧过程中的粉煤灰，废弃的电子垃圾等二次资源中。随着镓需求量的逐年增加，如何从二次资源中再生镓是当前的研究热点。本文综述二次资源中金属镓的赋存状态及提取回收的主要工艺技术，如酸碱溶出法，水热法，溶剂萃取法，氯化挥发法，真空蒸馏富集法，还原熔融法等，分析评价各工艺技术的分离效果和存在的问题，以求对二次资源中提取回收镓提供参考。

参考文献/References:

[1] 翟秀静,吕子剑.镓冶金[M].北京:冶金工业出版社,2010, 05
[2] Liu Z B, Li H X. Metallurgical process for valuable elements recovery from red mud—A review[J]. Hydrometallurgy, 2015, 155: 29-43
[3] 芦小飞,王磊,王新德,牛学坤.金属镓提取技术进展[J].有色金属,2008,60(4):105-108,114
[4] 李婷,辛志峰,徐梦,白林山,董永平,储向峰.两段碳酸化法分离氧化铝和氧化镓的研究[J].洁净煤技术,2016,22(1):105-108
[5] 仇振琢,魏旭华,陈莉.以循环碱液替代石灰乳提取镓[J]；化工冶金,1999,20(1):74-77
[6] R.A.Abdulvaliyev, A.Akcil, S.V, Gladyshev, E.A. Tastanov, K.O. Beisembekova, N.K. Akhmadiyeva, H. Deveci. Gallium and Vanadium Extraction from Red Mud of Turkish Alumina Refinery Plant: Hydrogarnet Process[J]. Hydrometallurgy, 2015, 157: 72-77
[7] Leveque, A, Helegorsky, J. The recovery of gallium from Bayer process aluminate solutions by liquid-liquid extraction[J]. International Solvent Extraction Conference, 1997: 439-442
[8] Borgess, P.P, Masson, I.O.C. Solvent extraction of gallium with Kelex 100 from Brazilian weak sodium aluminate solutions[J]. Minerals Engineering, 1994, 7(7) : 933-941
[9] 南娟茹,费作朋.拜耳法生产氧化铝提取伴生镓[J].百科论坛,2013,(14):373
[10] Puvvada G.V.K, Chandrasekhar K, Ramachandrarao P. Solvent extraction of gallium from an Indian Bayer process liquor using kelex-100[J]. Minerals Engineering, 1996, 9(10): 1049-1058
[11] H. Filik, R. Apak. A chelating ion exchang for Gallium recovery from alkaline solution using 5-Palmitoyl-8-hydroxyquinoline Immobilized on a nonpolar adsorbent[J]. Separation Science and Technology. 1998, 33(8): 1123-1134
[12] Hiroshi Okushita, Takeo Shimidzu. Selective separation of Ga3+ through membrane impregnated with N-octadecanoyl-N-phenylhydroxilamine[J]. Journal of Membrane Science.1995, 105: 43-49
[13] 宋嘉伟.盐酸浸出赤泥综合回收有价金属的基础研究[D].山西:太原理工大学,2013
[14] 路坊海,周登风,张华军.树脂吸附-酸脱附法在氧化铝生产流程中回收金属镓的应用[J].轻金属,2013,(7):8-12
[15] 韦文宾,何启贤.从湿法炼锌浸出渣中回收镓的试验研究[J].湿法冶金,2008,27(2):103-105
[16] 龙来寿.从冶锌工业废渣中综合回收镓、铟、锗的研究[D]. 广东:广东工业大学,2004
[17] Wu X L, Wu S K, Qin W Q, Ma X H, Niu Y J, Lai S S, Yang C R, Jiao F, Ren L Y. Reductive leaching of gallium from zinc residue[J]. Hydrometallurgy . 2012: 113–114, 195–199
[18] 吴雪兰.从锌浸出渣中回收镓锗的研究[D]. 湖南:中南大学,2013
[19] Akita, S;Rovira, M;Sastre, AM;Hyodo, N;Takeuchi H. Coacervation characteristics of nonionic surfactants and their application to metal separation[C]. International Symposium on Liquid-Liquid 2 Phase Flow and Transport Phenomena.1997
[20] T Kinoshitaa, S Akitaa, S Niib, F Kawaizumib, K Takahashib. Solvent extraction of gallium with non-ionic surfactants from hydrochloric acid solution and its application to metal recovery from zinc refinery residues[J]. Separation and Purification Technology. 2004, 37(2): 127-133
[21] T. Kinoshitaa, Y. Ishigakia, N. Shibataa, K. Yamaguchia, S. Akitaa, S. Kitagawab, H.Kondouc, S.Niic. Selective recovery of gallium with continuous counter-current foam separation and its application to leaching solution of zinc refinery residues[J]. Separation and Purification Technology. 2011, 78(2): 181-188
[22] Zahra Bahri , Bahram Rezai , Elaheh Kowsari. Selective separation of gallium from zinc using flotation: Effect ofsolution pH value and the separation mechanism[J]. Minerals Engineering. 2016, 86, 104-113
[23] 石太宏,汤兵,张秀娟.液膜法从湿法炼锌系统中提取镓的研究[J].稀有金属.1998,22(1):1-4
[24] 石太宏,王向德,万印华,张秀娟.D2EHPA与C5-7羟肟酸自硫酸介质中协同萃取Ga3+的液膜理论基础研究(Ⅰ)[J].膜科学与技术,1999,19(3):25-28
[25]石太宏,王向德,万印华,朱斌，张秀娟.P2O4与C5-7羟肟酸液膜体系自湿法冶锌系统中同步迁徙分别回收镓和锗(Ⅱ) [J].膜科学与技术.1999,19(4):34-38
[26] Shenjun Qin, Yuzhuang Sun, Yanheng Li, JinxiWang, Cunliang Zhao, Kang Gao. Coal deposits as promising alternative sources for gallium[J]. Earth-Science Reviews. 2015,150:95-101
[27] Gesser, H.D, Horsfall, G.A. The separation and concentration of gallium by polyurethane[J]. J. Chim. Phys., 1977, 74: 1072- 1076
[28] 曾青云.从粉煤灰中提取金属镓的实验研究[D].北京:中国地址大学,2007
[29] 何佳振.粉煤灰中金属镓的回收工艺研究[D]．湖南: 湘潭大学,2006
[30] 何佳振,胡晓莲,李运勇.从粉煤灰中回收金属镓的工艺研究[J]．粉煤灰,2002,(5): 23 －27
[31] Font, Orio, Querol, Xavier, Juan, Roberto, Casado, Raque, Ruiz,Carmen, López-Soler;Coca,Pilar, Pe?a, Francisco García. Recovery of gallium and vanadium from gasification fly ash[J]. Journal of Hazardous Materials. 2007, 139(3): 413-423.
[32] 张路平.粉煤灰中镓富集与浸出工艺研究[D].湖北:武汉科技大学,2014
[33] 曹毅臣.黄磷电尘灰中镓真空还原富集实验研究[D].云南:昆明理工大学,2012
[34] Zhang,Zhaohui, Zhang,Huabin, Hu,Yufang, Yang, Xiao, Yao, Shouzhuo. Novel surface molecularly imprinted material modified multi-walled carbon nanotubes as solid-phase extraction sorbent for selective extraction gallium ion from fly ash[J]. TALANTA. 2010, 82(1): 304-311
[35] 张朝晖,张华斌,胡宇芳,李艳杰,聂丽华.镓离子配合物印迹聚合物的研制及吸附性能研究[J].化学通报,2011,74(1):72-77
[36] Swain B, Mishra C, Kang L, Park KS, Lee CG, Hong HS. Recycling process for recovery of gallium from GaN an e-waste of LED industry through ball milling, annealing and leaching[J]. Environmental Research. 2015, 138: 401-408
[37] Basudev Swain, Chinmayee Mishra, Leeseung Kang, Kyung-Soo Park, Chan Gi Lee, Hyun Seon Hong, Jeung-Jin Park. Recycling of metal-organic chemical vapor deposition waste of GaN based power device and LED industry by acidic leaching : Process optimization and kinetics study[J]. Journal of Power Sources. 2015, 281: 265-271
[38]郭学益,李平,黄凯,刘荣义.从砷化镓工业废料中回收镓和砷的方法[P].中国:CN1693492,2005)
[39] Hyo Sook Lee, Chul Woo Nam. A study on the extraction of gallium from gallium arsenide scrap[J]. Hydrometallurgy. 1998, 49(1-2): 125-133
[40] Zhan L, Xia F;Ye Q, Xiang X, Xie B. Novel recycle technology for recovering rare metals (Ga, In) from waste light-emitting diodes[J]. Hazard Mater. 2015, 299: 388-394
[41] 王勤,杨柳,陈艳红,谭翠丽,严杰,王阳烨.废旧二极管中锗、镓、铟、硒的回收方法[P].中国: CN102951618B,2014) .
[42] 郝常明,黄雪菊.浅谈超临界流体萃取技术及其应用[J].医药工程设计杂志,2003,24(2)
[43] Zhou, Wei-Lung, Wang, Chih-Ta, Yang, Kai-Chiang, Huang, Yen-Hsiang. Removal of gallium ions from acidic aqueous solution by supercritical carbon dioxide extraction in the green separation process[J]. Journal of Hazardous Materials. 2008, 160(1): 6-12
[44] Bina Gupta, Niti Mudhar, Zareena Begum I, Indu Singh. Extraction and recovery of Ga3+ from waster material using Cyanex 923[J]. Hydrometallurgy.2007, 87: 18–26
[45] I.M. Ahmed, Y.A. El-Nadi, N.E. El-Hefny. Extraction of gallium(III) from hydrochloric acid by Cyanex 923 and Cyanex 925[J]. Hydrometallurgy.2013, 131-132: 24-28.

相似文献/References:

[1]胡　伟,熊大和.强磁选-重选联合工艺回收尾矿、尾渣中铁的研究[J].有色金属科学与工程,2010,(01):52.
　HU Wei,XIONG Da-he.On Iron Ore Recovery out of Mineral Processing Tailing and Smelting Tailing by Magnetic-gravity Process[J].,2010,(01预):52.
[2]管建红.采用脉动高梯度磁选机回收赤泥中铁的试验研究[J].有色金属科学与工程,2000,(04):15.
　GUAN Jiang-hong.Study on recovering Fe from red mud with SLon vertical ring and pulsating high gradient magnetic separator[J].,2000,(01预):15.
[3]司秀芬,邓佐国,徐廷华,等.赤泥提钪综述[J].有色金属科学与工程,2003,(02):28.
　SI Xiu-fen,DENG Zuo-guo,XU Ting-hua.Summarization of Extracting Scandium from Red Mud[J].,2003,(01预):28.
[4]荣旻.赤泥-钛白废酸综合回收中钪的萃取工艺研究余荣旻[J].有色金属科学与工程,2017,(04预):36.
　YU Rong-min.Technology of Extracting Scandium in the Comprehensive Recovery of Red Mud-Titanium White Waste Acid[J].,2017,(01预):36.
[5]余荣旻.赤泥-钛白废酸综合回收中钪的萃取工艺[J].有色金属科学与工程,2017,(04):31.[doi:10.13264/j.cnki.ysjskx.2017.04.006]
　YU Rongmin.Technology of extracting scandium in comprehensive recovery of red mud-titanium white waste acid[J].,2017,(01预):31.[doi:10.13264/j.cnki.ysjskx.2017.04.006]
[6]屈振民,张帅,张延玲.高铁赤泥制备CaO-SiO2-Fe2O3-Al2O3系微晶玻璃[J].有色金属科学与工程,2019,(04):34.[doi:10.13264/j.cnki.ysjskx.2019.04.006]
　QU Zhenmin,ZHANG Shuai,ZHANG Yanling.Preparation of CaO-SiO2-Fe2O3-Al2O3 system glass-ceramics from red mud with high iron[J].,2019,(01预):34.[doi:10.13264/j.cnki.ysjskx.2019.04.006]
[7]黄蒙蒙,李宏煦,刘召波.不同二次资源中镓提取方法的研究进展[J].有色金属科学与工程,2017,(01):21.[doi:10.13264/j.cnki.ysjskx.2017.01.004]
　HUANG Mengmeng,LI Hongxu,LIU Zhaobo.Research progress on gallium extraction from different secondary resources[J].,2017,(01预):21.[doi:10.13264/j.cnki.ysjskx.2017.01.004]

备注/Memo

备注/Memo:
参考文献
更新日期/Last Update: 2016-09-20