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[1].文章编号:2016070132-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征[J].有色金属科学与工程,2017,(01预):1-5.
 ZENG Xue-hua,LUO Yan-sheng,DI Bao-sheng,et al.Synthesis and characterization of 2-(2-benzimidazolyl)-6- methylpyridine Cu(I)Fe(II) heterodinuclear complex[J].,2017,(01预):1-5.
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文章编号:2016070132-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征(/HTML)
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《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2017年01期预
页码:
1-5
栏目:
出版日期:
2017-01-30

文章信息/Info

Title:
Synthesis and characterization of 2-(2-benzimidazolyl)-6- methylpyridine Cu(I)Fe(II) heterodinuclear complex
作者:
-
Author(s):
ZENG Xue-hua LUO Yan-sheng DI Bao-sheng XIA Yong QIU Lu CHEN Jing-lin
(School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China)
关键词:
一价铜苯并咪唑配体双膦配体异双核配合物晶体结构
分类号:
TF811
DOI:
-
文献标志码:
A
摘要:
以1,1′-双(二苯基膦)二茂铁(dppf)、2-(2-苯并咪唑基)-6-甲基吡啶(Hbmp)和[Cu(CH3CN)4](ClO4)作为起始原料,合成得到了一个铜(I)铁(II)杂金属双核配合物[Cu(Hbmp)(dppf)](ClO4) (1).X-射线单晶衍射结果表明:配合物1是一个铜(I)铁(II)异双核配合物,其中铜(I)离子采用四配位方式,分别与2个氮原子和2个磷原子相连接形成一个变形的四面体构型,而铁(II)离子镶嵌在2个环戊二烯基之间构成一个交错式夹心饼干构型.配合物1在355~460 nm有一个弱的低能量宽吸收峰,来源于铜(I)离子到Hbmp配体的金属到配体电荷转移跃迁(MLCT),含有一些dppf到Hbmp的配体到配体电荷转移跃迁(LLCT).

参考文献/References:

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相似文献/References:

[1]曾雪花,罗燕生,狄宝生,等.2-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征[J].有色金属科学与工程,2017,(01):94.[doi:10.13264/j.cnki.ysjskx.2017.01.016]
 ZENG Xuehua,LUO Yansheng,DI Baosheng,et al.Synthesis and characterization of 2-(2-benzimidazolyl)-6-methylpyridine Cu(I)Fe(II) heterodinuclear complex[J].,2017,(01预):94.[doi:10.13264/j.cnki.ysjskx.2017.01.016]

备注/Memo

备注/Memo:
收稿日期:2016-07-22基金项目:国家自然科学基金项目(21561013);江西省青年科学基金重大项目(20143ACB21017);江西省自然科学基金项目(20142BAB203001);江西理工大学清江青年英才支持计划资助项目通信作者:陈景林(1976– ),男,汉,博士,教授,主要从事光电信息功能材料与器件研究,E–mail:gzchenjinglin@126.com
更新日期/Last Update: 2016-09-20