|本期目录/Table of Contents|

[1]胡伟,钟盛文,李晓艳,等.LiNi0.55Co0.15Mn0.30O2三元正极材料的合成及电化学性能研究[J].有色金属科学与工程,2019,(04):6-10.
 HU Wei,ZHONG Shengwen,LI Xiaoyan,et al..30O2 cathode material[J].,2019,(04):6-10.
点击复制

LiNi0.55Co0.15Mn0.30O2三元正极材料的合成及电化学性能研究(/HTML)
分享到:

《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2019年04期
页码:
6-10
栏目:
出版日期:
2019-07-20

文章信息/Info

Title:
.30O2 cathode material
作者:
胡伟1钟盛文12李晓艳1黄景彪1彭康春1饶先发2邱世涛2
(1.江西江特锂电池材料有限公司,江西 宜春 336000;2.江西理工大学材料工程学院,江西 赣州 341000)
Author(s):
HU Wei ZHONG Shengwen LI Xiaoyan HUANG Jingbiao PENG Kangchun RAO XianfaQIU Shitao
(1 Jiangxi Jiangte Lithium-ion Battery Material Co.,Ltd, Yichun 336000, China; 2 Faculty of materials and chemical engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China)
关键词:
锂离子电池正极材料电化学性能
分类号:
TM912.9
DOI:
-
文献标志码:
A
摘要:
文中采用共沉淀法合成类球形氢氧化镍钴锰前驱体,经混料机与碳酸锂均匀混合,在氧化气氛下经过高温焙烧得到LiNi0.55Co0.15Mn0.30O2化学组分的三元正极材料.通过设计合理的配锂量、保温时间、气氛条件,并对烧制温度设计试验进行考察研究,最终优选出最佳工艺条件

参考文献/References:

[1] 陈鹏,肖冠,廖世军.具有不同组成的镍钴锰三元材料的最新研究进展[J]. 化工进展,2016,35 (1) 166-173.
[2] 姜华伟,刘亚飞,陈彦彬,等. 锂离子电池三元正极材料研究及应用进展[J]. 人工晶体学报,2018,47(10)2205-2211.
[3] 董生德, 周园, 海春喜. 用于锂离子电池镍钴锰三元正极材料的改性研究进展[J]. 高分子通报, 2018, (8):112-118.
[4] YOO G W , JANG B C, SON J T, et al. Novel design of core shell structure by NCA modification on NCM cathode material to enhance capacity and cycle life for lithium secondary battery[J]. Ceramics International, 2015, 41(1):1913-1916.
[5] Guilmard M, Croguennec L, Denux A, et al. Thermal Stability of Lithium Nickel Oxide Derivatives. Part I: LixNi1.02O2 and LixNi0.89Al0.16O2 (x = 0.50 and 0.30)[J]. Cheminform, 2004, 35(3):4476-4483.
[6] YANG X, WANG L, HU GE, et al. Layered Li[Ni0.5Co0.2Mn0.3]O2-Li2MnO3]O2 compounds by a simple combustion method [J]. Power Sources,2004,129 (2):288-295.[7] NOH H J,YOUN S J, YOON C S, et al. comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x=1/3,0.5,0.6,0.7,0.8 and 0.85) cathode material for lithium-ion batteries [J]. Power Sources,2003,233 (1):121-130.
[8] 唐爱东,黄可龙. 合成温度对六方Li-Ni-Co-Mn-O固溶体结构和性能的影响[J]. 金属学报,2005, 41(12):1280-1284.
[9] KIM N Y, YIM T, SONG J H,et al. Microstructural study on degradation mechanism of layered LiNi0.6Co0.2Mn0.2O2 cathode materials by analytical transmission electron microscopy[J]. Journal of Power Sources 2016,(307):641-648.
[10] HOANG K, JOHANES M. Defect physics and chemistry in layered mixed transition metal oxide cathode materials: (Ni,Co,Mn) vs (Ni,Co,Al)[J]. Chem. Mater, 2016, (28):1325-1334.
[11] WANG Y, FENG Z, YANG S Z, et al. Layered oxides-LiNi1/3Co1/3Mn1/3O2 as anode electrode for symmetric rechargeable lithium-ion batteries[J]. Journal of Power Sources, 2018, (378):516-521.
[12] LIN Y K,LU C H. Preparation and electrochemical properties of layer-structured LiNi1/3Co1/3Mn1/3-yAlyO2[J]. Power Sources, 2009, (189):353-358.
[13] LOVE C T, JOHANNES M D, SWIDER-LYONS K. Thermal stability of delithiated Al-substituted Li(Ni1/3Co1/3Mn1/3)O2 cathodes[J]. ECS Trans, 2010, (25):231-240.
[14] CHIO J M, MANTHIRAM A. Role of chemical and structural stabilities on the electrochemical properties of layered LiNi1/3Co1/3Mn1/3O2 cathodes[J]. Electrochem. Soc. 2005, (152):A1714-A1718.
[15] IDEMOTO Y, MATSYI T. Thermodynamic stability, crystal structure, and cathodic performance of LixNi1/3Co1/3Mn1/3O2 depend on the synthetic process and Li content [J].Solid State Ionics, Diffusion & Reactions, 2008, 179(17-18):625-635.
[16] 邱世涛, 钟盛文, 李婷婷,等. Cu掺杂LiNi0.6Co0.2Mn0.2O2的电化学性能[J]. 有色金属科学与工程, 2018(5):21-25.
[17] 彭弯弯, 徐唱, 李之锋,等. 面密度和压实密度对锂离子电池快充性能的影响[J].有色金属科学与工程, 2017, 8(3):69-73.
[18] 罗熳, 蒋文全, 韩雪, 等. 锂离子电池浓度梯度正极材料LiNi0.643Co0.055Mn0.302O2的合成与表征[J]. 高等学校化学学报, 2018, 39(1):148-156.
[19] 林清云, 关文浩, 孟杰,等. 锂离子电池正极材料Li[Ni1/3Mn1/3Co1/3]O2的制备与显微结构研究[J]. 电子显微学报, 2018(1):8-14.
[20] 程波明, 杨金猛, 刘宝禄, 等. 烧结温度对LiNi0.8Co0.15Al0.05O2结构和电化学性能的影响[J]. 有色金属科学与工程, 2018, 48(4):51-56.

相似文献/References:

[1]钟盛文a,张金波a,封志芳a,等.合成条件对锂离子正极材料LiMn2O4电性能影响[J].有色金属科学与工程,2011,(02):24.
 ZHONG Sheng-wena,ZHANG Jin-boa,FENG Zhi-fanga,et al.Synthesizing Conditions’Effects on the Electrical Properties of LiMn2O4 as the Cathode Materials of Li-ion Batteries[J].,2011,(04):24.
[2]徐宝和,吴甜甜,钟盛文,等.Si4+掺杂对富锂Li[Li0.15Mn0.575Ni0.275]1-xSixO2材料性能的影响[J].有色金属科学与工程,2012,(02):24.
 XU Bao-he,WU Tian-tian,ZHONG Sheng-wen,et al.Comparative study of Si-doped Li[Li0.15Mn0.575Ni0.275]1-xSixO2 prepared by ion exchange[J].,2012,(04):24.
[3]廖春发,陈辉煌,陈子平.稀土掺杂锂离子电池正极材料LiCoO_2的影响研究[J].有色金属科学与工程,2004,(02):33.
 LIAO Chun-fa,CHEN Hui-huang,CHEN Zi-ping.Influence of Doping Rare Earth on the LiCoO2 as Lithium-ion Positive Material[J].,2004,(04):33.
[4]李金辉,郑 顺,熊道陵,等.废旧锂离子电池正极材料有价资源回收方法[J].有色金属科学与工程,2013,(04):29.
 LI Jin-hui,ZHENG Shun,XIONG Dao-ling,et al.Methods for valuable resource recovery from cathode materials of spent lithium ion battery[J].,2013,(04):29.
[5]陈鹏a,b,钟盛文a,等.烧结气氛对无钴镍基正极材料LiNi0.7Mn0.3O2性能的影响[J].有色金属科学与工程,2015,(04):52.[doi:10.13264/j.cnki.ysjskx.2015.04.011]
 CHEN Penga,b,ZHONG Shengwena,et al.Effect of sintering atmosphere on electrochemical performance of cobalt free nickel rich LiNi0.7Mn0.3O2 cathode material[J].,2015,(04):52.[doi:10.13264/j.cnki.ysjskx.2015.04.011]
[6]胡伟,钟盛文.富锂锰基正极材料的改性及电化学性能研究*[J].有色金属科学与工程,2016,(05预):840.
 HU Wei,ZHONG Sheng-wen.Synthesis and electrochemical properties of modified Mn-based cathode material rich in lithium[J].,2016,(04):840.
[7]郭进康,钟盛文,王强,等.分散剂对石墨烯正极浆料的影响[J].有色金属科学与工程,2016,(06预):1.
 GUO Jinkang,ZHONG Shengwen,WANG Qiang,et al.Effect of dispersant on cathode slurry for graphene[J].,2016,(04):1.
[8]钟盛文*.,黄冰..锂过量对钙钛矿型Li3/8Sr7/16Ta3/4Hf1/4O3固体电解质性能的影响[J].有色金属科学与工程,2017,(01预):72.
 ZHONG Shengwen*.HUANG Bing..Effects of excess lithium salt on the properties of perovskite-type solid electrolyte Li3/8Sr7/16Ta3/4Hf1/4O3[J].,2017,(04):72.
[9]郭进康,钟盛文,王强,等.分散剂对石墨烯正极浆料的影响[J].有色金属科学与工程,2016,(06):73.[doi:10.13264/j.cnki.ysjskx.2016.06.012]
 GUO Jinkang,ZHONG Shengwen,WANG Qiang,et al.Effect of dispersant on cathode slurry of graphene[J].,2016,(04):73.[doi:10.13264/j.cnki.ysjskx.2016.06.012]
[10]钟盛文,黄冰.锂过量对钙钛矿型Li3/8Sr7/16Ta3/4Hf1/4O3固体电解质性能的影响[J].有色金属科学与工程,2017,(01):70.[doi:10.13264/j.cnki.ysjskx.2017.01.012]
 ZHONG Shengwen,HUANG Bing.Effects of excess lithium salt on properties of perovskite-type solid electrolyte Li3/8Sr7/16Ta3/4Hf1/4O3[J].,2017,(04):70.[doi:10.13264/j.cnki.ysjskx.2017.01.012]
[11]钟盛文,王玉娥,张 骞,等.LiNi0.5Mn0.5O2的合成及其AA电池电化学性能[J].有色金属科学与工程,2010,(02):11.
 ZHANG Sheng-wen,WANG Yue,ZHANG Qian,et al.Synthesis and Electrochemical Properties of LiNi0.5Mn0.5O2 as Cathode Material for AA Lithium Ion Batteries[J].,2010,(04):11.
[12]钟盛文,封志芳,谢 敏.熔盐法合成LiMn1/3Ni1/3Co1/3O2及AA电池的电化学性能[J].有色金属科学与工程,2011,(01):9.
 ZHONG Sheng-wen,FENG Zhi-fang,XIE Min.Synthesis and Performances of Li (Mn1/3Ni1/3Co1/3) O2 as the AA Type of Lithium-ion Batteries by Melting Salt[J].,2011,(04):9.
[13]廖春发,郭守玉,陈辉煌,等.锂离子电池正极材料的制备研究现状[J].有色金属科学与工程,2003,(02):34.
 LIAO Chun-fa,GUO Shou-yu,CHEN Hui-huang.Research Status on Cathode Materials of Li-ion Battery[J].,2003,(04):34.
[14]宋晋阳,叶红齐,董 虹,等.正极材料LiNi1/3Co1/3Mn1/3O2的Mg掺杂及电化学性能[J].有色金属科学与工程,2013,(03):30.
 SONG Jin-yang,YE Hong-qi,DONG Hong,et al.Mg-doping and electrochemical properties of Li(Ni1/3Co1/3Mn1/3)O2 cathode material[J].,2013,(04):30.
[15]胡伟,钟盛文,黄冰.富锂锰基正极材料的改性及电化学性能研究[J].有色金属科学与工程,2014,(04):32.[doi:10.13264/j.cnki.ysjskx.2014.04.007]
 HU Wei,ZHONG Shengwen,HUANG Bing.Optimizing electrochemical properties in Li-rich Mn-based cathode material[J].,2014,(04):32.[doi:10.13264/j.cnki.ysjskx.2014.04.007]
[16]尹壮,周红伟,丁夏楠,等.一维纳米LiNi1/3Co1/3Mn1/3O2纤维的合成及性能研究[J].有色金属科学与工程,2015,(03预):40.
 Zhuang Yin,Hongwei Zhou,Xianan Ding,et al.Synthesis and performance study of one-dimensional LiNi1/3Co1/3Mn1/3O2 nanofiber prepared by electrospinning[J].,2015,(04):40.
[17]尹壮,周红伟,丁夏楠,等.一维纳米LiNi1/3Co1/3Mn1/3O2纤维的合成及性能研究[J].有色金属科学与工程,2015,(02):32.[doi:10.13264/j.cnki.ysjskx.2015.02.006]
 YIN Zhuang,ZHOU Hongwei,DING Xianan,et al.Synthesis and performance study of one-dimensional LiNi1/3Co1/3Mn1/3O2 nanofiber[J].,2015,(04):32.[doi:10.13264/j.cnki.ysjskx.2015.02.006]
[18]陈军,梅文捷,曾敏,等.羧基取代镍酞菁配合物的合成及其电化学性能研究[J].有色金属科学与工程,2015,(05):45.[doi:10.13264/j.cnki.ysjskx.2015.05.009]
 CHEN Jun,MEI Wenjie,ZENG Min,et al.Synthesis and properties of carboxyl substituted nickel phthalocyanineas cathode materials for lithium ion batteries[J].,2015,(04):45.[doi:10.13264/j.cnki.ysjskx.2015.05.009]
[19]刘熙林,钟盛文,梅文捷,等.Li1.07(Ni0.4Mn0.53)1-xAlxO2正极材料的合成与性能[J].有色金属科学与工程,2015,(05):63.[doi:10.13264/j.cnki.ysjskx.2015.05.012]
 LIU Xilin,ZHONG Shengwen,MEI Wenjie,et al.Synthesis and properties of Li1.07(Ni0.4Mn0.53)1-xAlxO2 as cathode materials for lithium ion batteries[J].,2015,(04):63.[doi:10.13264/j.cnki.ysjskx.2015.05.012]
[20].熔盐法合成LiMn1/3Ni1/3Co1/3O2及AA电池的电化学性能[J].有色金属科学与工程,2016,(05预):2025.
 ZHONG Sheng-wen,FENG Zhi-fang,XIE Min.Synthesis and Performances of Li (Mn1/3Ni1/3Co1/3) O2 as the AA Type of Lithium-ion Batteries by Melting Salt[J].,2016,(04):2025.

备注/Memo

备注/Memo:
收稿日期:2019-05-10基金项目:国家基金资助项目(51874151)
更新日期/Last Update: 2019-06-26