|本期目录/Table of Contents|

[1]-(-苯并咪唑基)--甲基吡啶-’-联萘-’-双二苯膦铜(I)配合物.文章编号:202007032[J].有色金属科学与工程,2020,(05):31-36.
 JU Peng,PENG Dan,CHEN Xingwei,et al.Cu(I) Complex with 2-(2-Benzimidazolyl)-6-methylpyridine and 1,1’-Binaphthal-2,2’-bisdiphenylphosphine[J].,2020,(05):31-36.
点击复制

文章编号:202007032(/HTML)
分享到:

《有色金属科学与工程》[ISSN:1674-9669/CN:36-1311/TF]

卷:
期数:
2020年05期
页码:
31-36
栏目:
出版日期:
2020-09-20

文章信息/Info

Title:
Cu(I) Complex with 2-(2-Benzimidazolyl)-6-methylpyridine and 1,1’-Binaphthal-2,2’-bisdiphenylphosphine
作者:
2-(2-苯并咪唑基)-6-甲基吡啶-11’-联萘-22’-双二苯膦铜(I)配合物
(江西理工大学材料冶金化学学部,江西 赣州 341000)
Author(s):
JU Peng PENG Dan CHEN Xingwei ZENG Fanzhong SHU Wengui PENG Liangliang CHEN Jinglin
(Department of Materials, Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China)
关键词:
一价铜苯并咪唑双膦光致发光
分类号:
TF811
DOI:
-
文献标志码:
A
摘要:
以[Cu(CH3CN)4](ClO4)、1,1’-联萘-2,2’-双二苯膦(BINAP)和2-(2-苯并咪唑基)-6-甲基吡啶(Hbmp)为起始原料,合成得到一例铜(I)单核配合物[Cu(Hbmp)(BINAP)](ClO4) (1),并对其结构和光物理性质进行了表征。X-射线单晶衍射表明,配合物1的一价铜离子与Hbmp上的2个N和BINAP上的2个P相连接,产生一个以一价铜离子为中心的变形四面体。配合物1在340~450 nm范围有一个弱的低能量宽吸收,其归属于Cu(I)到Hbmp的金属到配体电荷转移(MLCT)跃迁。配合物1在溶液和固态均具有良好的光致发光性质。

参考文献/References:

[1].TROSE M, LAZREG F, CHANG T, et al. Neutral dinuclear copper(I)-NHC complexes: synthesis and application in the hydrosilylation of ketones[J]. ACS Catalysis, 2017, 7: 238-242.
[2].PERRUCHAS S, GOFF X, MARO S, et al. Mechanochromic and thermochromic luminescence of a copper iodide cluster[J]. Journal of the American Chemical Society, 2010, 132: 10967-10969.
[3].CHEN X L, YUAN L H, He L H, et al. A sublimable dinuclear cuprous complex showing selective luminescence vapochromism in the crystalline state[J]. Inorganic Chemistry, 2019, 58: 14478-14489.
[4].尹少云, 张露尹, 王政, 等. “眼镜”状碘化亚铜配合物的调光和双光子发光性质[J]. 高等学校化学学报, 2020, 41(4): 646-651.
[5].朱晗, 寇军锋, 刘丰祎, 等. 一个三维三唑类铜配位聚合物的合成及催化亚甲基蓝降解性能和机理研究[J]. 广东化工, 2020, 47(2): 12-13.
[6].柴轲, 高月泽, 张静. 新型环硫脲亚铜配合物的结构及固体发光性质[J]. 中国科学院大学学报, 2019, 36(5): 620-625.
[7].PELLEI M, GANDIN V, MARINELLI M, et al. Novel triazolium based 11th group NHCs: synthesis, characterization and cellular response mechanisms[J]. Dalton Transactions, 2015, 44: 21041-21052.
[8].SCHINABECK A, J.LEITL M, YERSIN H, et al. Dinuclear Cu(I) complex with combined bright TADF and phosphorescence. Zero-field splitting and spin?lattice relaxation effects of the triplet state[J]. Journal of Physical Chemistry Letters, 2018, 9: 2848-2856.
[9].CHEN J L, GUO Z H, LUO Y S, et al. Luminescent mononuclear Cu(I) triphenylphosphine complexes based on methylated 5-trifluoromethyl-3-(2′-pyridyl)-1,2,4-triazole ligands[J]. New Journal of Chemistry, 2016, 40: 5325-5332.
[10].CHEN J L, GUO Z H, YU H G, et al. Luminescent dinuclear copper(I) complexes bearing 1,4-bis(diphenyl phosphine)butane and functionalized 3-(2′-pyridyl)pyrazole mixed ligands[J]. Dalton Transactions, 2016, 45: 696-750.
[11].何丽华, 陈景林, 曹兴付, 等. 2-(2-苯并咪唑基)-6-甲基吡啶铜(I)溴化物的合成与发光[J]. 有色金属科学与工程, 2012, 3(3): 6-9.
[12].陈景林, 宋鹏, 温和瑞, 等. 双核铜(I)配合物的合成及其固态发光性质的研究[J]. 有色金属科学与工程, 2010, 1(1): 27-29.
[13].LUO Y S, CHEN J L, ZENG X H, et al. A highly stable and luminescent mononuclear Cu(I) bis{5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole} complex[J]. Chinese Chemical Letters, 2017, 28: 1027-1030.
[14].KELLER S, PRESCIMONE A, C.CONSTABLE E, et al. Copper(I) and silver(I) complexes of 9,9-dimethyl4,5-bis(di-tert-butylphosphino)xanthene: photophysical properties and structural rigidity under pressure[J]. Photochemical & Photobiological Sciences, 2018, 17: 375-385.
[15].LIN Y, CHEN D H, YU R, et al. Photo- and electro-luminescence of three TADF binuclear Cu(I) complexes with functional tetraimine ligands[J]. Journal of Materials Chemistry C, 2017, 5: 4495-4504.
[16].HAMZE R, L.PELTIER J, SYLVINSON D, et al. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime[J]. Science, 2019, 363: 601-606.
[17].ZINK D M, VOLZ D, BAUMANN T, et al. Heteroleptic dinuclear copper(I) complexes for application in organic light-emitting diodes[J]. Chemistry of Materials, 2013, 25: 4471-4486.
[18].ANDRES-TOME I, FYSON J, DIAS F B, et al. Copper(I) complexes with bipyridyl and phosphine ligands: a systematic study[J]. Dalton Transactions, 2012, 41: 8669-8674.
[19].FEMONI C, MUZZIOLI S, PALAZZI A, et al. New tetrazole-based Cu(I) homo- and heteroleptic complexes with various P^P ligands: synthesis, characterization, redox and photophysical properties[J]. Dalton Transactions, 2013, 42: 997-1010.
[20].SUN W H, HAO P, ZHANG S, et al. Iron(II) and cobalt(II) 2-(benzimidazolyl)-6-(1-(arylimino)ethyl) pyridyl complexes as catalysts for ethylene oligomerization and polymerization[J]. Organometallics, 2007, 26: 2720-2734.
[21].KUBAS G J, MONZYK B, CRUMBLISS A L, et al. Tetrakis(acetonitrile)copper(I) hexafluorophosphate[J]. Inorganic Syntheses, 1979, 19: 90-92.
[22].曾雪花, 罗燕生, 陈景林, 等. 2-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征[J]. 有色金属科学与工程, 2017, 8(1): 94-98.
[23].DI B S, CHEN J L, LUO Y S, et al. Synthesis, structures and photophysical properties of copper(I) 2-(2-benzimidazolyl)-6-methylpyridine complexes with different diphosphine ligands[J]. Polyhedron, 2016, 119: 525-531.
[24].CHEN J L, CAO X F, GU W, et al. Phosphorescent copper(I) complexes bearing 2-(2-benzimidazolyl)- 6-methylpyridine and phosphine mixed ligands[J]. Inorganic Chemistry Communications, 2011, 14: 1894-1897.
[25].HE L H, CHEN J L, WANG J Y, et al. Structures and luminescence properties of two copper(I) halide complexes featuring 2-(2-benzimidazolyl)-6-methylpyridine[J]. Chinese Chemical Letters, 2012, 23: 1169-1172.

相似文献/References:

[1].文章编号:2016070132-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征[J].有色金属科学与工程,2017,(01预):1.
 ZENG Xue-hua,LUO Yan-sheng,DI Bao-sheng,et al.Synthesis and characterization of 2-(2-benzimidazolyl)-6- methylpyridine Cu(I)Fe(II) heterodinuclear complex[J].,2017,(05):1.
[2]曾雪花,罗燕生,狄宝生,等.2-(2-苯并咪唑基)-6-甲基吡啶铜(I)铁(II)异双核配合物的合成与表征[J].有色金属科学与工程,2017,(01):94.[doi:10.13264/j.cnki.ysjskx.2017.01.016]
 ZENG Xuehua,LUO Yansheng,DI Baosheng,et al.Synthesis and characterization of 2-(2-benzimidazolyl)-6-methylpyridine Cu(I)Fe(II) heterodinuclear complex[J].,2017,(05):94.[doi:10.13264/j.cnki.ysjskx.2017.01.016]

备注/Memo

备注/Memo:
收稿日期:2020-07-29基金项目:国家自然科学基金项目(21861018);江西省主要学科学术和技术带头人项目(20182BCB22010);江西省自然科学基金重点项目联合资助(20192ACBL20013);赣州市科技创新人才计划项目;江西理工大学清江青年英才支持计划资助项目通信作者:陈景林(1976– ),男,汉,博士,教授,主要从事光电信息功能材料与器件研究,E–mail:gzchenjinglin@126.com
更新日期/Last Update: 2020-09-18